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The "steam pot" of Papin
XVIIth Century
FLUIDS
Moist air
Mixtures of ideal gas or of ideal gas and steam
Ideal gas
Water
Refrigerants R134a and R22
Ammonia
Carbon Dioxide
Methane
Water_Ammonia
DIAGRAMS
Psychrometric
diagram
Temperature -
Entropy
Enthalpy - Presure
Phase diagram
and Enthalpy
- Concentration diagram of Water-Ammonia

The florentine
termoscope
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THERPROP
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A Software
Program for Calculating and Graphing Thermodynamic Properties of Fluids
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What is THERPROP ?
THERPROP is a software product aimed at calculating
thermodynamic properties of the fluids more frequently used in industrial
processes.
THERPROP allows the representation and the analysis of
fluid transformations over the usual thermodynamic diagrams.
How does it Work
The approach adopted by THERPROP is based on the
graphs normally employed in Thermodynamic, as the graphs
Temperature-Entropy (T,S) and Enthalpy-Pressure (H,P).
Once the fluid and the type of graph have been
selected, the desidered graph appears on the screen; you may draw on
the graph the isoproperty lines, i.e. the lines at constant pressure
or enthalpy etc.
Clicking one point of the graph, THERPROP
calculates the properties of that point, pressing the mouse button
over one point and moving the mouse over a different point, THERPROP
calculates the properties of both the points involved, as well as
their variations.
When the process involves a pressure variation
THERPROP interpretates the process as an expansion or compression: an
isentropic efficiency may be specified to allow a correct process
evaluation.
This feature makes quick and easy the evaluation of
a simple process that actually requires much more time if carried out
by handy interpolation through tables or by the use of more complex
software products.
Working
with several fluids at same time
You may draw in one session as many graphs as you need of
different fluids, you may keep them open or closed and switch from each
other
Systems of units
Two systems of units are available: the international
system referred as SI and the British system. The unit of bar is used in SI
for pressure.
A system can be defined for each graph you generate; you
may also monitor in the other system the results generated using one system.
The fluids
Fluids recognized by THERPROP are:
Moist air
Mixtures of ideal gas or by ideal gas and steam
Ideal gas
Water
Refrigerants R134a and R22
Ammonia
Carbon Dioxide
Methane
Water_Ammonia
The capability of THERPROP to deal with water_ammonia and
mixtures of ideal gas and steam, widely extends the fields of application of
the program. In the field of power generation, where THERPROP was first
conceived, you may face non conventional process as the Kalina one or you
may face non usual process as those involving geothermal fluids.
THERPROP may be extended by the user to deal with any
additional single component real fluid provided that he has available tables
of thermodynamic properties.
The Diagrams
Moist air is represented by the usual psychrometric
diagram complete of adiabatic saturation lines.
The psychrometric diagram of moist air generated using
the data file Moistair.tab. Clicking one point the properties of that point,
including the wet bulb temperature, are calculated. You have the option to
refer the properties to the unit of dry gas, as common practice, or to the
unit of moist gas. You may also draw the adiabatic saturation line passing
through the point of your interest. If you are interested in the low
temperature field you may use the Zoom option to enlarge a selected area or
you may change the scale limits.
Mixtures of ideal gas and steam, as well as pure ideal
gas or mixtures of ideal gas, are represented by the Temperature-Entropy
(T,S) diagram.
Two phase, single component real fluids are represented
by diagrams Enthalpy-Pressure (H,P) and Temperature-Entropy (T,S).
Isoproperty lines may be drawn on both the diagrams.
Mixtures of Water and Ammonia are represented by the
phase diagram and by the graph Enthalpy vs Ammonia mass fraction at Vapour
Liquid Equilibrium.
The Tables
THERPROP operates also as the conventional programs aimed
at thermodynamic properties calculation. You may avoid the use of graphs and
specify through the keyboard the fluid state. This approach is useful for
generating tables of properties to be used eventually later for generating
graphs.
Assessing
fluid transformation
If you want analyze a process generate the T, S diagram.
A process is normally accomplished by a number of steps: each step involves
a transformation of the fluid physical state. You may easily calculate the
fluid properties at the ends of each step. THERPROP records them and
calculates the variations. If a step involves a fluid expansion or
compression, you may specify the isentropic efficiency to allow THERPROP a
correct process evaluation.
Let we consider the expansion process of steam
between the pressures of 100 bar and 1 bar. The physical state of the steam
before the expansion is labeled with the number 1 in the T,S
diagram. To
determine the final state after expansion specify the isentropic
efficiency of the transformation, place the mouse pointer over the initial
state in the T,S diagram, click and move the mouse towards the isobar
of the final state with the same entropy of the initial.
After having released the mouse button, over the T,S
diagram is drawn the straight line that connects the final state of the
transformation to the initial.
And ...
You may print and save your work. Diagrams are saved as
bitmap and you may manipulate and use them in your reports and presentations.
Where does it
Help?
In all the cases you
need a quick calculation of the more common thermodynamic properties as
for instance: enthalpy, entropy or density, you may use THERPROP. THERPROP replaces
the printed thermodynamic diagrams and can be also used to
evaluate the fluid
properties variation during a real transformation
like expansion or compression.
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